Temperature, time, dew point setting, minimum and maximum moisture guidelines for Polypropylene (PP), Rigid Thermoplastic Polyurethane (ETPU),  Nylon 6 (PA6), Nylon 66 (PA66), Polyketone (PK), Polyphenylene Sulfide (PPS), Polyphthalamide (PPA), Polyetherimide (PEI), Polyethersulfone (PES), and Polyetheretherketone (PEEK)  Temperature (rear feed zone, center transition zone, front metering zone, nozzle, melt, and mold) guidelines for PP, ETPU,  PA6, PA66, PK, PPS, PPA, PEI, PES, and PEEK 

Performance Products & Solutions (PP&S) achieved a new record for return on sales at 7.2 percent and further reduced its working capital as a percent of sales to 4.3 percent. This strength was most notably evidenced by our hiring last year of Brad Richardson as CFO and Michael Garratt as president of PP&S. PolyOne’s stock performance has significantly outpaced the S&P 500 index and the S&P Mid Cap 400 Chemicals index. 12.31.09 6.30.10 12.31.10 6.30.11 12.31.11 6.30.12 12.31.12 6.30.13 12.31.13 2007 2008 2009 2010 2011 2012 2013 SPECIALTY PLATFORM OPERATING INCOME % OF TOTAL*^ 1.50 1.20 .90 .60 .30 0 2007 2008 2009 2010 2011 2012 2013 ADJUSTED EARNINGS PER SHARE*† * 2010–2013 Specialty Operating Income is restated for the divestiture of the Resin Business ^Operating Income excludes Corporate Charges * 2010–2013 adjusted EPS is restated for the divestiture of the Resin Business † EPS excluding special items and equity income from SunBelt 2007 2008 2009 2010 2011 2012 2013 * 2010–2013 adjusted return on sales is restated for the divestiture of the Resin Business ° Operating Income as a percentage of sales, excluding special items and equity income from SunBelt ADJUSTED RETURN ON SALES*º 8 6 4 2 0 % P E R C E N TA G E 80 60 40 20 0 % P E R C E N TA G E Operating Income % Specialty PP&S Distribution Specialty Platform Operating Income % of Total ROIC** (after-tax) 2006 1.5% 5.5% 2.6% 6.0% 5.0% 2013 9.4% 7.2% 5.9% 62.0% 9.1% 2015 TARGET 12%–16% 9%–12% 6%–7.5% 65%–75% 15% **ROIC is defined as adjusted OI divided by the sum of average debt and equity over a 5 quarter period 200 160 120 80 40 0 2007 2008 2009 2010 2011 2012 2013 SPECIALTY PLATFORM OPERATING INCOME* * 2010–2013 Operating Income is restated for the divestiture of the Resin Business 400 300 200 100 0 % P E R C E N TA G E POLYONE STOCK (POL) PERFORMANCE VERSUS S&P P O L S&P MID CAP 400 CHEMICALS S&P 500 United States Securities and Exchange Commission Washington, DC 20549 FORM 10-K Í ANNUAL REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2013 ‘ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to .

PG 43309 BU PP PG 43312 BU PP GREEN PEARL PP

TRANS BLUE PP ORANGE PP UV GREEN PP UV

PG 39120 PU PP PG 39123 RD PP PG 39126 GY PP

PG 274090.00 PEARL PU PP PP BRONZE MC-87398PP PP FR 8-6 LMS-1000

PEACOCK BLUE TINT PP PG 34640 PP PG 34624 YE PP

BLUE PP PG 360102.00 WT PP PG 360103.00 OR PP

PP ELFE GREEN-F BLUE 534C PP BLUE 285C PP

PG 66969.00 GN PP SL PG 66971.00 GN PP SL PP FR 8-6 LMS-1000