PP FR 8-6E NAT PP 600 HR-7001 PP FR 7A11-9009

PG 19395 RD PP PG 19398 GN PP PG 19399 WT PP

PP GREEN NON TIO2 V2 PP YELLOW C PP FR 8-6 LMS-1000

PP GREEN CAP 390C PP RED STRAW 1795C PP METALLIC SILVER

TP NIR BLACK PP TP BLACK PP GREEN 4224 PP

ORANGE 7599C PP MAROON 7629C PP PG 408838.00 PK PP

PP HUNTER GREEN SEA BLUE 2394 PP SC MED BLUE 2194 PP SC

Performance Products & Solutions (PP&S) achieved a new record for return on sales at 7.2 percent and further reduced its working capital as a percent of sales to 4.3 percent. This strength was most notably evidenced by our hiring last year of Brad Richardson as CFO and Michael Garratt as president of PP&S. PolyOne’s stock performance has significantly outpaced the S&P 500 index and the S&P Mid Cap 400 Chemicals index. 12.31.09 6.30.10 12.31.10 6.30.11 12.31.11 6.30.12 12.31.12 6.30.13 12.31.13 2007 2008 2009 2010 2011 2012 2013 SPECIALTY PLATFORM OPERATING INCOME % OF TOTAL*^ 1.50 1.20 .90 .60 .30 0 2007 2008 2009 2010 2011 2012 2013 ADJUSTED EARNINGS PER SHARE*† * 2010–2013 Specialty Operating Income is restated for the divestiture of the Resin Business ^Operating Income excludes Corporate Charges * 2010–2013 adjusted EPS is restated for the divestiture of the Resin Business † EPS excluding special items and equity income from SunBelt 2007 2008 2009 2010 2011 2012 2013 * 2010–2013 adjusted return on sales is restated for the divestiture of the Resin Business ° Operating Income as a percentage of sales, excluding special items and equity income from SunBelt ADJUSTED RETURN ON SALES*º 8 6 4 2 0 % P E R C E N TA G E 80 60 40 20 0 % P E R C E N TA G E Operating Income % Specialty PP&S Distribution Specialty Platform Operating Income % of Total ROIC** (after-tax) 2006 1.5% 5.5% 2.6% 6.0% 5.0% 2013 9.4% 7.2% 5.9% 62.0% 9.1% 2015 TARGET 12%–16% 9%–12% 6%–7.5% 65%–75% 15% **ROIC is defined as adjusted OI divided by the sum of average debt and equity over a 5 quarter period 200 160 120 80 40 0 2007 2008 2009 2010 2011 2012 2013 SPECIALTY PLATFORM OPERATING INCOME* * 2010–2013 Operating Income is restated for the divestiture of the Resin Business 400 300 200 100 0 % P E R C E N TA G E POLYONE STOCK (POL) PERFORMANCE VERSUS S&P P O L S&P MID CAP 400 CHEMICALS S&P 500 United States Securities and Exchange Commission Washington, DC 20549 FORM 10-K Í ANNUAL REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2013 ‘ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to .

PG 65623.00 BU PP PG 65622.00 BU PP PG 65640.00 BU PP

Additives and Colorants for PP-R and PP-RCT Pipe Systems Learn more about our additives and colorants portfolio for PP-R and PP-RCT pipe systems Geotexiles - PP Nonwoven Manufacturer